Let be a ring with identity and denote the category of complexes of -modules. In this paper we study the homotopy categories arising from projective (resp. injective) complexes as well as Gorenstein projective (resp. Gorenstein injective) modules. We show that the homotopy category of projective complexes over , denoted , is always well generated and is compactly generated provided is so. Based on this result, it will be proved that the class of Gorenstein projective complexes is precovering, whenever is a commutative noetherian ring of finite Krull dimension. Furthermore, it turns out that over such rings the inclusion functor $\iota : \K(\RGPrj)\hookrightarrow \KR\iota_{\rho}\K(\RGPrj)R$ modules. Similar, or rather dual, results for the injective (resp. Gorenstein injective) complexes will be provided. If has a dualising complex, a triangle-equivalence between homotopy categories of projective and of injective complexes will be provided. As an application, we obtain an equivalence between the triangulated categories and , that restricts to an equivalence between and , whenever is commutative, noetherian and admits a dualising complex.

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