We present a new matrix-valued isospectral ordinary differential equation that asymptotically block-diagonalizes zero-diagonal Jacobi matrices employed as its initial condition. This o.d.e.\ features a right-hand side with a nested commutator of matrices, and structurally resembles the double-bracket o.d.e.\ studied by R.W.\ Brockett in 1991. We prove that its solutions converge asymptotically, that the limit is block-diagonal, and above all, that the limit matrix is defined uniquely as follows: For even, a block-diagonal matrix containing blocks, such that the super-diagonal entries are sorted by strictly increasing absolute value. Furthermore, the off-diagonal entries in these blocks have the same sign as the respective entries in the matrix employed as initial condition. For odd, there is one additional block containing a zero that is the top left entry of the limit matrix. The results presented here extend some early work of Kac and van Moerbeke.

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