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An open quantum system with multiple levels coupled to a bosonic environment at zero temperature is investigated systematically using the non-Markovian quantum-state-diffusion (QSD) method [W. T. Strunz, L. Di'osi, and N. Gisin, Phys. Rev. Lett. 82, 1801 (1999)]. We have established exact time-local QSD equations for a set of interesting multilevel open systems, including high-spin systems, multiple-transition atomic models, and multilevel atomic models driven by time-dependent external fields. These exact QSD equations have paved the way to evaluate the dynamics of open multilevel atomic systems in the general non-Markovian regimes without any approximation.

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