In this paper, we introduce the notion of modified Rota-Baxter operators of non-zero weight on -Lie algebras and provide some examples. Next, we give various constructions of modified Rota-Baxter operators of non-zero weight according to constructions of -Lie algebras. Furthermore, we define a cohomology of modified Rota-Baxter operators of non-zero weight on -Lie algebras with coefficients in a suitable representation. As an application, we study formal deformations of modified Rota-Baxter operators of non-zero weight that are generated by the above-defined cohomology. In the final part of the paper, we construct two -algebra structures whose Maurer-Cartan elements correspond to relative and absolute modified Rota-Baxter -Lie algebra structures of nonzero weight, respectively. Lastly, we compare our -algebraic approach with the deformation-controlling -algebra for relative Rota-Baxter -Lie operators developed by Hou, Sheng, and Zhou.

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