We present the first X-ray polarimetric observation of the extreme high-synchrotron-peaked blazar 1ES 1101–232, conducted by the Imaging X-ray Polarimetry Explorer (IXPE). The data analysis incorporates simultaneous and quasi-simultaneous observations from Swift-XRT and NuSTAR. Our results reveal a significant detection of X-ray polarization in the 2–6 keV band at a confidence level (CL) of 6.6, with a polarization degree of and an electric vector position angle (EVPA) of . An even higher polarization degree of with an EVPA of is observed within a narrower time interval, at a CL of 4.3. During the IXPE observational campaign, the X-ray spectrum of 1ES 1101–232 exhibits a clear soft-to-hard spectral evolution in the 0.3–10 keV band, although no significant flux variability is detected. Additionally, a clockwise hysteresis loop is identified in the flux–photon index plane. These findings collectively indicate that the X-ray emission from 1ES 1101–232 originates in a region characterized by a well-ordered magnetic field through synchrotron radiation.

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