Electrons can be reflected at an interface between two metals because of a dielectric barrier or different properties of the Fermi surface. Andreev reflection allows to directly measure normal reflection when one of the metals is a superconductor. We have investigated normal reflection at interfaces between non-magnetic normal metals and superconducting Nb (Tc = 9.2 K) and Al (Tc = 1.2 K). The distribution of the values of the relative strength of the interface barrier, Z, for a number of contacts of a specific metal combination shows a well-defined peak which can be attributed to Fermi surface mismatch. Our reflection coefficients are generally smaller than those predicted theoretically or those derived from proximity-effect studies of normal-superconductor bi-layers.

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