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We study ionic electrodiffusion modeled by the Nernst–Planck equations describing the evolution of ionic species in a three-dimensional incompressible fluid flowing through a porous medium. We address the long-time dynamics of the resulting system in the three-dimensional whole space . We prove that the -th spatial derivatives of each ionic concentration decays to zero in with a sharp rate of order . Moreover, we investigate the behavior of the relative entropy associated with the model and show that it blows up in time with a sharp growth rate of order .

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