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Classical bremsstrahlung of a massless scalar field is studied in gravity mediated ultra-relativistic collisions with impact parameter of two massive point particles in the presence of non-compact or toroidal extra dimensions. The spectral and angular distribution of the scalar radiation are analyzed, while the total emitted energy is found to be strongly enhanced by a dependent power of the Lorentz factor . The direct radiation amplitude from the accelerated particles is shown to interfere destructively (in the first two leading ultra-relativistic orders) with the one due to the interaction in the frequency regime in all dimensions.

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