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In the present paper we set up a connection between the indices of the Tits algebras of a simple linear algebraic group and the degree one parameters of its motivic -invariant. Our main technical tool are the second Chern class map and Grothendieck’s -filtration. As an application we recover some known results on the -invariant of quadratic forms of small dimension; we describe all possible values of the -invariant of an algebra with orthogonal involution up to degree 8 and give explicit examples; we establish several relations between the -invariant of an algebra with orthogonal involution and the -invariant of the corresponding quadratic form over the function field of the Severi-Brauer variety of .

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