We introduce a notion of L-dendriform algebra due to several different motivations. L-dendriform algebras are regarded as the underlying algebraic structures of pseudo-Hessian structures on Lie groups and the algebraic structures behind the -operators of pre-Lie algebras and the related -equation. As a direct consequence, they provide some explicit solutions of -equation in certain pre-Lie algebras constructed from L-dendriform algebras. They also fit into a bigger framework as Lie algebraic analogues of dendriform algebras. Moreover, we introduce a notion of $\mathcal O$-operator of an L-dendriform algebra which gives an algebraic equation regarded as an analogue of the classical Yang-Baxter equation in a Lie algebra.

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