This contribution aims at studying the behaviour of the classical sample moment estimator, , as a function of the number of available samples , in the case where the random variables are positive, have finite moments at all orders and are naturally of the form $X= \exp YYe^{-y^\rho}$. This class of laws encompasses and generalizes the classical example of the log-normal law. This form is motivated by a number of applications stemming from modern statistical physics or multifractal analysis. Borrowing heuristic and analytical results from the analysis of the Random Energy Model in statistical physics, a critical moment is defined as the largest statistical order up to which the sample mean estimator correctly accounts for the ensemble average $\E X^qnq_c(n)$ is then proposed. Its statistical performance are studied analytically and illustrated numerically in the case of \emph{i.i.d.} samples. A simple modification is proposed to explicitly account for correlation amongst the observed samples. Estimation performance are then carefully evaluated by means of Monte-Carlo simulations in the practical case of correlated time series.

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