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In the large coupling constant limit, we obtain an asymptotic expansion in powers of of the derivative of the spectral shift function corresponding to the pair $\big(P_\mu=P_0+\mu W(x),P_0=-\Delta+V(x)\big),W(x)W(x)\sim w_0(\frac{x}{|x|})|x|^{-\delta}\delta>nw_0\in {\mathcal C}^\infty(\mathbb S^{n-1};,\mathbb R_+).\mathbb S^{n-1}$ is the unite sphere of the space and is a large parameter. The potential is real-valued, smooth and periodic with respect to a lattice in .

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