Optical absorption and structure of impurity Ni${}^{2+}$ center in tungstate-tellurite glass

Absorption spectra of Ni${}^{2+}$ ions in 22WO${}_3$–78TeO${}_2$ tungstate-tellurite glass were studied and Ni${}^{2+}$ extinction coefficient spectral dependence was derived in the 450 – 2700 nm wavelength range. Computer modeling of the glass structure proved Ni${}^{2+}$ ions to be in trigonal-distorted octahedral environment in the tungstate-tellurite glass. Tanabe-Sugano diagram for such an environment was calculated and good description of the observed spectrum of Ni${}^{2+}$ ion was obtained. Basing on both absorption spectral range width and the extinction coefficient, nickel should be considered among the most strongly absorbing impurities in the tellurite glasses.