Entanglement witnesses (EWs) constitute one of the most important entanglement detectors in quantum systems. Nevertheless, their complete characterization, in particular with respect to the notion of optimality, is still missing, even in the decomposable case. Here we show that for any qubit-qunit decomposable EW (DEW) W the three statements are equivalent: (i) the set of product vectors obeying \bra{e,f}W\ket{e,f}=0 spans the corresponding Hilbert space, (ii) W is optimal, (iii) W=Q^{\Gamma} with Q denoting a positive operator supported on a completely entangled subspace (CES) and \Gamma standing for the partial transposition. While, implications and are known, here we prove that (iii) implies (i). This is a consequence of a more general fact saying that product vectors orthogonal to any CES in C^{2}\otimes C^{n} span after partial conjugation the whole space. On the other hand, already in the case of C^{3}\otimes C^{3} Hilbert space, there exist DEWs for which (iii) does not imply (i). Consequently, either (i) does not imply (ii), or (ii) does not imply (iii), and the above transparent characterization obeyed by qubit-qunit DEWs, does not hold in general.

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