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We study maximal bipartite entanglement in valence-bond states and show that the average bipartite entanglement , between a sub-system of two spins and the rest of the system, can be maximized through a homogenized superposition of the valence-bond states. Our derived maximal rapidly increases with system size and saturates at its maximum allowed value. We also demonstrate that our maximal states are ground states of an infinite range Heisenberg model (IRHM) and represent a new class of resonating-valence-bond (RVB) states. The entangled RVB states produced from our IRHM are robust against interaction of spins with both local and global phonons and represent a new class of decoherence free states.

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