We study dependence of the atmospheric and fluxes on the deviations of the 2-3 mixing from maximal, , on the -octant and on the neutrino mass splitting $\Delta m_{32}^2\theta_{23}-$deviation effect and the octant asymmetry are derived. We present conservative estimations of sensitivities of the iron (magnetized) calorimeter detectors (ICAL) to these parameters. ICAL can establish the -deviation at higher than 3 confidence level if with the exposure of 1 Mtonyr. Sensitivity to the octant is low for zero or very small 1-3 mixing, but it can be substantially enhanced for $\theta_{13} > 3^\circ\Delta m_{32}^2\nu\bar\nu0.8\times 10^{-4}^2\sigma\cdot$yr exposure, and the present MINOS result can be excluded at confidence level. We discuss possible ways to further improve sensitivity of the magnetized spectrometers.

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