Let be a compact connected simple Lie group and let be a generalized flag manifold. In this article we focus on an important invariant of , the so called -root system , and we introduce the notion of symmetric -triples, that is triples of -roots such that . We describe their properties and we present an interesting application on the structure constants of , quantities which are straightforward related to the construction of the homogeneous Einstein metric on . Next we classify symmetric -triples for generalized flag manifolds with second Betti number , and we treat also the case of full flag manifolds , where is a maximal torus of . In the last section we construct the homogeneous Einstein equation on flag manifolds with five isotropy summands, determined by the simple Lie group . By solving the corresponding algebraic system we classify all -invariant (non-isometric) Einstein metrics, and these are the very first results towards the classification of homogeneous Einstein metrics on flag manifolds with five isotropy summands.

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