We present a comprehensive study of mid-infrared neutral hydrogen (H~) emission lines in 79 nearby (d 200 ) young stars using JWST/MIRI. We aim to identify mid-infrared H~ transitions that can serve as reliable accretion diagnostics in young stars, and evaluate their utility in deriving physical conditions of the accreting gas. We identify and measure 22 H~ transitions in the MIRI wavelength regime (5-28 ) and perform LTE slab modelling to remove the H\textsubscript{2}O contribution from selected H~ transitions. We find that mid-IR H~ line emission is spatially compact, even for sources with spatially extended [Ne~] and [Fe~] jets, suggesting minimal contamination from extended jet. Although Pfund~ (H~~6–5) and Humphreys~ (H~~7–6) are the strongest lines, they are blended with HO transitions. This blending necessitates additional processing to remove molecular contamination, thereby limiting their use as accretion diagnostics. Instead, we identify the H~~(8–6) at 7.502 and H~~(10–7) at 8.760 transitions as better alternatives, as they are largely unaffected by molecular contamination and offer a more reliable means of measuring accretion rates from MIRI spectra. We provide updated empirical relations for converting mid-IR H~ line luminosities into accretion luminosity for 6 different H~ lines in the MIRI wavelength range. Moreover, comparison of observed line ratios with theoretical models shows that MIR H~ lines offer robust constraints on the hydrogen gas density in accretion columns, 10 to 10 cm in most stars, with some stars exhibiting lower densities (~cm), approaching the optically thin regime.

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