The purpose of this memoir is to study pre-Lie algebras up to homotopy with divided powers, and to use this algebraic structure for the study of mapping spaces in the category of operads. We define a new notion of algebra called -algebra which characterizes the notion of -algebra. We also define a notion of a Maurer-Cartan element in complete -algebras which generalizes the classical definition in Lie algebras. We prove that for every complete brace algebra , and for every , the tensor product is endowed with the structure of a complete -algebra, and define the simplicial Maurer-Cartan set associated to as the Maurer-Cartan set of . We compute the homotopy groups of this simplicial set, and prove that the functor satisfies a homotopy invariance result, which extends the Goldman-Millson theorem in dimension . As an application, we give a description of mapping spaces in the category of non-symmetric operads in terms of this simplicial Maurer-Cartan set. We etablish a generalization of the latter result for symmetric operads.

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