We study the non-degeneracy invariant of complex Enriques surfaces in families. Our first main result shows that cannot increase under specialization. The second main result is the conclusion of the computation of the non-degeneracy invariant for the families of -generic surfaces introduced by Brandhorst and Shimada. Of the previously known cases, only satisfy , which is the non-degeneracy invariant of a general Enriques surface. The remaining families studied in this article also have non-generic non-degeneracy. To compute this, we produce upper bounds on by refining this invariant into two others: the Fano and Mukai non-degeneracy invariants, which are related to two different classes of projective realizations of Enriques surfaces. As a result, we find the first known examples of Enriques surfaces with .

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