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In this paper we consider pseudo-Riemannian spaces of arbitrary signature for which all of their polynomial curvature invariants vanish (VSI spaces). We discuss an algebraic classification of pseudo-Riemannian spaces in terms of the boost weight decomposition and define the - and ${\bf N}{\bf N}$-property then it is a VSI space. We then use this result to construct a set of metrics that are VSI. All of the VSI spaces constructed possess a geodesic, expansion-free, shear-free, and twist-free null-congruence. We also discuss the related Walker metrics.

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