A unit vector for characterizing the spin polarization of free electron

New degrees of freedom having the form of a unit vector are identified for characterizing the spin polarization of free electron. It is shown that when only the spin is considered, the non-commutativity of the Cartesian components of the Pauli vector allows us to use the azimuthal angle of a second direction, denoted by unit vector $\mathbf{I}$, with respect to the quantization direction to characterize the spin polarization. The rotation of $\mathbf{I}$ through an angle about the quantization axis leads to a rotation of the spin polarization vector through twice the angle about the same axis. Discussions are also made in Heisenberg picture as well. Upon utilizing this approach to a free electron and letting the quantization direction for each plane wave be the wave vector, we arrive at a representation in which the unit vector $\mathbf{I}$ functions as an independent index to characterize the spin polarization.