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We give the complete classification of left-invariant sub-Riemannian structures on three dimensional Lie groups in terms of the basic differential invariants. This classifications recovers other known classification results in the literature, in particular the one obtained in [Falbel-Gorodski, 1996] in terms of curvature invariants of a canonical connection. Moreover, we explicitly find a sub-Riemannian isometry between the nonisomorphic Lie groups and , where denotes the group of orientation preserving affine maps on the real line.

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