The event-by-event dynamical fluctuations in kaon-to-proton and proton-to-pion ratios have been studied in dependence on center–of–mass energies of nucleon–nucleon collisions . Based on changing phase space volume which apparently is the consequence of phase transition from hadrons to quark–gluon plasma at large , the single–particle distribution function is assumed to be rather modified. Varying and phase space volume are implemented in the grand–canonical partition function, especially at GeV, so that hadron resonance gas model, when taking into account the experimental acceptance and quark phase space occupation factor , turns to be able to reproduce the dynamical fluctuations in and ratios over the entire range of .

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