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We have studied a quinary Fe-based superconductor SrVFeAsO by the measurements of x-ray diffraction, x-ray absorption, M"{o}ssbauer spectrum, resistivity, magnetization and specific heat. This apparently undoped oxyarsenide is shown to be self doped via electron transfer from the V ions. We observed successive magnetic transitions within the VO layers: an antiferromagnetic transition at 150 K followed by a weak ferromagnetic transition at 55 K. The spin orderings within the VO planes are discussed based on mixed valence of V and V.

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