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We investigate the optical conductivity as a function of temperature with light polarized along the in-plane orthorhombic - and -axes of Ba(FeCo)As for =0 and 2.5 under uniaxial pressure. The charge dynamics at low frequencies on these detwinned, single domain compounds tracks the anisotropic transport properties across their structural and magnetic phase transitions. Our findings allow us to estimate the dichroism, which extends to relatively high frequencies. These results are consistent with a scenario in which orbital order plays a significant role in the tetragonal-to-orthorhombic structural transition.

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