A vector subspace of is called unital operator system if if and only if and the identity operator $I_n \in \clsnC^(\cls)C^\IM_n(\IC)\cls$. We prove that a unital complete order isomorphism between two such operator systems and of has a unique extension to a -isomorphism if and only if and are having equal set of complete ranks. The operator system $\cls = \mbox{span}{v_iv_j^*:1 \le i,j \le d }$ is uniquely determined for a unital completely positive map of index $d \ge 1$. As an application of our main result, we explore this correspondence and characterize up to co-cycle conjugacy all extreme points in the convex set of unital completely positive maps on . Using the main result, we also characterize up to co-cycle conjugacy all extreme elements in the convex set of normalized trace preserving unital completely positive maps on .

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