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We study edge states of non-centrosymmetric superconductors where spin-singlet d-wave pairing mixes with spin-triplet p (or f)-wave one by spin-orbit coupling. For dxy-wave pairing, the obtained Andreev bound state has an anomalous dispersion as compared to conventional helical edge modes. A unique topologically protected time-reversal invariant Majorana fermion appears at the edge. The charge conductance in the non-centrosymmetric superconductor junctions reflects the anomalous structures of the dispersions, particularly the time-reversal invariant Majorana fermion is manifested as a zero bias conductance peak.

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