The relative Grothendieck group is the free abelian group generated by the isomorphism classes of complex algebraic varieties over modulo the “scissor relation”. The motivic Hirzebruch class ${T_y}*: K_0(\m V /X) \to H^{BM}(X) \otimes \bQ[y]$ is a unique natural transformation satisfying that for a nonsingular variety the value ${T_y}_([X \xrightarrow {\op {id}X} X])X \xrightarrow {id_X} X$ is the Poincar'e dual of the Hirzebruch cohomology class of the tangent bundle . It “unifies” the well-known three characteristic classes of singular varieties: MacPherson’s Chern class, Baum-Fulton-MacPherson’s Todd class (or Riemann-Roch) and Goresky-MacPherson’s L-class or Cappell-Shaneson’s L-class. In this paper we construct a bivariant relative Grothendieck group so that it equals the original relative Grothendieck group when is a point. We also construct a unique Grothendieck transformation $T_y: \bK_0(\m V/X \to Y) \to \bH(X \to Y) \otimes \bQ[y]$ satisfying a certain normalization condition for a smooth morphism so that it equals the motivic Hirzebruch class ${T_y}: K_0(\m V /X) \to H_^{BM}(X) \otimes \bQ[y]Yy =0T_0: \bK_0(\m V/X \to Y) \to \bH(X \to Y) \otimes \bQ$ is a “motivic” lift of Fulton-MacPherson’s bivariant Riemann-Roch $\ga_{td}^{\op {FM}}:\bK_{alg}(X \to Y) \to \bH(X \to Y) \otimes \bQ$.

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