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The article is devoted to Bc->Bs+n pi, Bc->Bs*+n pi decays with n=1, 2, 3, 4. In the framework of factorization theorem the branching fractions of these processes can be written as convolution of hard part, describing Bc->Bs W, Bc->Bs* W vertices, and spectral functions, that correspond to transition of virtual -boson into a final pi-meson system. These functions were obtained from the fit of experimental data on -lepton decay and electron-positron annihilation. Using different sets of Bc->Bs decay form-factors we present branching fractions and distributions over the invariant mass of the final pi-meson system.

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