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We consider diatomic systems in which the kinetic energy of the electrons is treated in a simple relativistic model. The Born-Oppenheimer approximation is assumed. We investigate questions of stability, deducing bounds on the number of electrons, the binding energy and the equilibrium bond distance . We use a known localization argument adopted to the present relativistic setting, with particular consideration of the critical point of stability, as well as the recently proved relativistic Scott correction.

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