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We investigate the behavior of the Schmidt gap, the von Neumann entanglement entropy, and the non-stabiliserness in proximity to the classical phase transition of the one-dimensional long-range transverse-field Ising model (LRTFIM). Leveraging the time-dependent variational principle (TDVP) within a tensor-network formulation, we simulate thermal states through their purified tensor-network representations. Our results show that these observables, typically regarded as hallmarks of quantum criticality, exhibit pronounced and coherent signatures even at a classical thermal transition, highlighting the emergence of quantum complexity as the system nears thermal criticality.

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