A pseudo-primitive word with respect to an antimorphic involution \theta is a word which cannot be written as a catenation of occurrences of a strictly shorter word t and \theta(t). Properties of pseudo-primitive words are investigated in this paper. These properties link pseudo-primitive words with essential notions in combinatorics on words such as primitive words, (pseudo)-palindromes, and (pseudo)-commutativity. Their applications include an improved solution to the extended Lyndon-Sch"utzenberger equation u_1 u_2 … u_l = v_1 … v_n w_1 … w_m, where u_1, …, u_l \in {u, \theta(u)}, v_1, …, v_n \in {v, \theta(v)}, and w_1, …, w_m \in {w, \theata(w)} for some words u, v, w, integers l, n, m \ge 2, and an antimorphic involution \theta. We prove that for l \ge 4, n,m \ge 3, this equation implies that u, v, w can be expressed in terms of a common word t and its image \theta(t). Moreover, several cases of this equation where l = 3 are examined.

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