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The internal structure of the exotic and pentaquarks remains an open question. To address this, we demonstrate that pion emission serves as a sensitive probe by calculating its properties within a molecular scenario using the chiral quark model and coupled-channel effects. Our results reveal a strong dependence of the decay widths on the internal structure and spatial wave functions. We therefore expect this study to stimulate experimental measurements of these decays, which are crucial for determining the nature of these states and guiding the search for further molecular partners.

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