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A rotational band with five -ray transitions ranging from 2 to 12 states was identified in Ar. This band is linked through transitions from the excited 2, 4 and 6 levels to the low-lying states; this determines the excitation energy and the spin-parity of the band. The deduced transition quadrupole moment of 1.45$^{+0.49}_{-0.31} eb$ indicates that the band has a superdeformed shape. The nature of the band is revealed by cranked Hartree–Fock–Bogoliubov calculations and a multiparticle–multihole configuration is assigned to the band.

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