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We present the theory of radiative association of atoms and molecules, and we apply it to the (H-H) van der Waals complex. We discuss the possibility for the H ion to be formed in the interstellar medium in an environment with abundant ionized molecular hydrogen H. The observation of H would also be a probe for the presence of H in the interstellar medium. By computing the electronic structure of the H ion, we determine its dipole moment, bound states, rotational constants, predissociated vibrational resonances and their lifetimes, and suggest a way to detect the ion in the interstellar medium.

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