Let be a Coxeter system and suppose that is fully commutative (in the sense of Stembridge) and has a reduced expression beginning (respectively, ending) with . If there exists such that and do not commute and (respectively, ) is no longer fully commutative, we say that is left (respectively, right) weak star reducible by with respect to . In this paper, we classify the fully commutative elements in Coxeter groups of types and affine that are irreducible under weak star reductions. In a sequel to this paper, the classification of the weak star irreducible elements in a Coxeter system of type affine will provide the groundwork for inductive arguments used to prove the faithfulness of a generalized Temperley–Lieb algebra of type affine by a particular diagram algebra.

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