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Let be a smooth curve in given by an equation F=0 of degree . In this paper we consider elementary transformations of linear pfaffian representations of . Elementary transformations can be interpreted as actions on a rank 2 vector bundle on with canonical determinant and no sections, which corresponds to the cokernel of a pfaffian representation. Every two pfaffian representations of can be bridged by a finite sequence of elementary transformations. Pfaffian representations and elementary transformations are constructed explicitly. For a smooth quartic, applications to Aronhold bundles and theta characteristics are given.

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