In two recent papers, the author has developed a theory of graded annihilators of left modules over the Frobenius skew polynomial ring over a commutative Noetherian ring of prime characteristic , and has shown that this theory is relevant to the theory of test elements in tight closure theory. One result of that work was that, if is local and the -module structure on the injective envelope of the simple -module can be extended to a structure as a torsion-free left module over the Frobenius skew polynomial ring, then is -pure and has a tight closure test element. One of the central results of this paper is the converse, namely that, if is -pure, then has a structure as a torsion-free left module over the Frobenius skew polynomial ring; a corollary is that every -pure local ring of prime characteristic, even if it is not excellent, has a tight closure test element. These results are then used, along with embedding theorems for modules over the Frobenius skew polynomial ring, to show that every excellent (not necessarily local) -pure ring of characteristic must have a so-called `big’ test element.

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