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A new construction method of -matrix is given. Let be a C-bialgebra with a comultiplication . For two states and of which satisfy certain conditions, we construct a unitary -matrix of the C-bialgebra on the tensor product of GNS representation spaces associated with and . The set satisfies a kind of Yang-Baxter equation. Furthermore, we show a nontrivial example of such -matrices for a non-quasi-cocommutative C-bialgebra.

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