Vertices of the 4-dimensional semi-regular polytope, and its symmetry group of order 576 are represented in terms of quaternions with unit norm. It follows from the icosian representation of root system. The quaternionic root system of splits as the vertices of 24-cell and the \textit{snub 24-cell} under the symmetry group of the which is one of the maximal subgroups of the group as well as . It is noted that the group is isomorphic to thesemi-direct product of the Weyl group of with the cyclic group of order 3 denoted by , the Coxeter notation for which is . We analyze the vertex structure of the and decompose the orbits of under the orbits of . The cell structure of the snub 24-cell has been explicitly analyzed with quaternions by using the subgroups of the group . In particular, it has been shown that the dual polytopes 600-cell with 120 vertices and 120-cell with 600 vertices decompose as 120=24+96 and 600=24+96+192+288 respectively under the group . The dual polytope of the is explicitly constructed. Decompositions of the Archimedean polytopes under the symmetry of the group are given in the appendix.

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