The cross section for radiative thermal neutron capture on ($\He3 +n \to \He4 +\gammahen$ reaction) is calculated based on heavy-baryon chiral perturbation theory. The relevant M1 operators are derived up to next-to-next-to-next-to-leading order (NLO). The initial and final nuclear wave functions are obtained from the rigorous Faddeev-Yakubovski equations for five sets of realistic nuclear interactions. Up to NLO, the M1 operators contain two low-energy constants, which appear as the coefficients of non-derivative two-nucleon contact terms. After determining these two constants using the experimental values of the magnetic moments of the triton and , we carry out a parameter-free calculation of the cross section. The results are in good agreement with the data.

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