Although frequency multiplexing of information has revolutionized the field of classical communications, the color degree of freedom (DOF) has been used relatively little for quantum applications. We experimentally demonstrate a new hybrid quantum gate that transfers polarization entanglement of non-degenerate photons onto the color DOF. We create, for the first time, high quality, discretely color-entangled states (with energy bandgap up to 8.4 THz) without any filtering or postselection, and unambiguously verify and quantify the amount of entanglement (tangle, 0.6110.009) by reconstructing a restricted density matrix; we generate a range of maximally entangled states, including a set of mutually unbiased bases for an encoded qubit space. The technique can be generalized to transfer polarization entanglement onto other photonic DOFs, like orbital angular momentum.

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