This paper investigates the geometric and algebraic interplay between F-manifolds and a newly defined class of structures termed F-algebras. We specialize our study to the category of F-Lie groups, characterized by a Lie group whose associated commutative and associative product of vector fields is left-invariant. We construct a canonical connection on Lie groups uniquely determined by the F-algebraic data, and subsequently characterize its curvature tensor and holonomy Lie algebra. A central feature of our investigation is the introduction of the Poisson-algebra distribution, arising from a canonical Poisson subalgebra within the F-algebra. We establish the integrability of this distribution, which induces a foliation of the F-Lie group and facilitates a local splitting theorem. The theoretical framework is illustrated through an in-depth analysis of the Heisenberg Lie algebra.

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