Let be a metric space with doubling measure, a nonnegative self-adjoint operator in satisfying the Davies-Gaffney estimate, a concave function on of strictly lower type and for all $t\in (0,\infty).H_{\omega,L}({\mathcal X})$ via the Lusin area function associated to the heat semigroup, and the BMO-type space . The authors then establish the duality between and ; as a corollary, the authors obtain the -Carleson measure characterization of the space . Characterizations of , including the atomic and molecular characterizations and the Lusin area function characterization associated to the Poisson semigroup, are also presented. Let and be a Schr"odinger operator, where $V\in L^1_{}({\mathbb R}^n)$ is a nonnegative potential. As applications, the authors show that the Riesz transform is bounded from to ; moreover, if there exist such that and {\normalsize} is a convex function on , then several characterizations of the Orlicz-Hardy space , in terms of the Lusin-area functions, the non-tangential maximal functions, the radial maximal functions, the atoms and the molecules, are obtained. All these results are new even when for all and .

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