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We report As NMR measurements in CaFeAs, made under applied pressures up to 0.83 GPa produced by a standard clamp pressure cell. Our data reveal phase segregation of paramagnetic (PM) and antiferromagnetic (AFM) phases over a range of pressures, with the AFM phase more than 90 % dominant at low temperatures. In situ RF susceptibility measurements indicate the presence of superconductivity. As spin-lattice relaxation experiments indicate that the As nuclei sample the superconductivity while in the magnetically-ordered environment.

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