This paper introduces and systematically studies Weyl-type, Witt-type, and non-associative algebras defined over expolynomial rings – commutative rings generated by exponential functions , exponentials of exponentials , and power functions for in an additive subgroup of a characteristic zero field . We establish several fundamental structural results: scalar extensions preserve both the algebraic structure and simplicity; intermediate subalgebras associated with subgroups remain simple; the algebra of graded derivations is isomorphic to a semidirect product ; tensor products over disjoint variable sets decompose naturally into larger algebras; and a complete isomorphism criterion is given, showing that isomorphism depends precisely on the orbit of the parameter under the automorphism group of and the equality of the deformation parameter . These theorems generalize classical results on Weyl and Witt algebras, provide new families of simple algebras, and offer a foundation for further research in deformation theory, representation theory, and cohomology.

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