The electric-quadrupole coupling constant of the ground states of the proton drip line nucleus Na( = 2, = 447.9 ms) and the neutron-deficient nucleus Na( = 3/2, = 22.49 s) in a hexagonal ZnO single crystal were precisely measured to be $|eqQ/h| = 690 \pm 12\pm\beta$-ray detecting nuclear magnetic resonance technique under presence of an electric-quadrupole interaction. A electric-quadrupole coupling constant of Na in the ZnO crystal was also measured to be kHz. The electric-quadrupole moments were extracted as Na) = 10.3 0.8 fm and Na) = 14.0 1.1 fm, using the electric-coupling constant of Na and the known quadrupole moment of this nucleus as references. The present results are well explained by shell-model calculations in the full -shell model space.

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