Green's function of fully anharmonic lattice vibration

Motivated by the discovery of superconductivity in beta-pyrochlore oxides, we study property of rattling motion coupled with conduction electrons. We derive the general expression of the Green’s function of fully anharmonic lattice vibration within the accuracy of the second order perturbation of electron-ion interaction by introducing self-energy, vertex-correction, and normalization factor for each transition. Using the expression, we discuss the characteristic properties of the spectral function in the entire range from weakly anharmonic potential to double-well case, and calculate NMR relaxation rate due to the two phonon Raman process.