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It is shown how classes of Fredholm Pfaffians can be computed in terms of canonical, auxiliary Riemann-Hilbert problems as soon as the main kernel in the Pfaffian is either of additive Hankel composition or of truncated Wiener-Hopf type. Akhiezer-Kac asymptotic results for the Fredholm Pfaffians are then derived as natural consequences of the Riemann-Hilbert characterisation.

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